Spatial-temporal variability of metal pollution across an industrial district, evidencing the environmental inequality in Sao Paulo

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dc.contributorSistema FMUSP-HC: Faculdade de Medicina da Universidade de São Paulo (FMUSP) e Hospital das Clínicas da FMUSP
dc.contributor.authorLOCOSSELLI, Giuliano Maselli
dc.contributor.authorMOREIRA, Tiana Carla Lopes
dc.contributor.authorCHACON-MADRIZ, Katherine
dc.contributor.authorARRUDA, Marco Aurelio Zezzi
dc.contributor.authorCAMARGO, Evelyn Pereira de
dc.contributor.authorKAMIGAUTI, Leonardo Yoshiaki
dc.contributor.authorTRINDADE, Ricardo Ivan Ferreira da
dc.contributor.authorANDRADE, Maria de Fatima
dc.contributor.authorANDRE, Carmen Diva Saldiva de
dc.contributor.authorANDRE, Paulo Afonso de
dc.contributor.authorSINGER, Julio M.
dc.contributor.authorSAIKI, Mitiko
dc.contributor.authorZACCARELLI-MARINO, Maria Angela
dc.contributor.authorSALDIVA, Paulo Hilario Nascimento
dc.contributor.authorBUCKERIDGE, Marcos Silveira
dc.date.accessioned2020-10-15T14:38:38Z
dc.date.available2020-10-15T14:38:38Z
dc.date.issued2020
dc.description.abstractAlthough air pollution decreased in some cities that shifted from an industrial to a service-based economy, and vehicular emission regulation became more restrictive, it is still a major risk factor for mortality worldwide. In central Sao Paulo, Brazil, air quality monitoring stations and tree-ring analyses revealed a decreasing trend in the concentrations of particulate matter and metals. Such trends, however, may not be observed in industrial districts located in the urban periphery, where the usual mobile sources may be combined with local stationary sources. To evaluate environmental pollution in an industrial district in southeastern Sao Paulo, we assessed its spatial variability, by measuring magnetic properties and concentrations of Al, Ba, Ca, Cl, Cu, Fe, K, Mg, Mn, P, S, Sr, Zn in the bark of 62 trees, and its temporal trends, by measuring Cd, Cu, Ni, Pb, V, Zn in tree rings of three trees. Source apportionment analysis based on tree barks revealed two clusters with high concentrations of metals, one related to vehicular and industrial emissions (Al, Ba, Cu, Fe, Zn) in the east side of the industrial cluster, and the other related to soil resuspension (Cu, Zn, Mn) in its west side. These patterns are also supported by the magnetic properties of bark associated with iron oxides and titanium-iron alloy concentrations. Dendrochemical analyses revealed that only the concentrations of Pb consistently decreased over the last four decades. The concentrations of Cd, Cu, Ni, V, and Zn did not significantly decrease over time, in contrast with their negative trends previously reported in central Sao Paulo. This combined biomonitoring approach revealed spatial clusters of metal concentration in the vicinity of this industrial cluster and showed that the local population has not benefited from the decreasing polluting metal concentrations in the last decades.eng
dc.description.indexMEDLINEeng
dc.description.sponsorshipSao Paulo Research FoundationFundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [FAPESP 2013/21728-2, 2015/25511-3, 2017/10544-9]
dc.description.sponsorshipConselho Nacional the Desenvolvimento Cientifico e Tecnologico [CNPq 304126/2015-2]
dc.description.sponsorshipCAPES, Coordination for the Improvement of Higher Education PersonnelCAPES
dc.identifier.citationENVIRONMENTAL POLLUTION, v.263, article ID 114583, 8p, 2020
dc.identifier.doi10.1016/j.envpol.2020.114583
dc.identifier.eissn1873-6424
dc.identifier.issn0269-7491
dc.identifier.urihttps://observatorio.fm.usp.br/handle/OPI/37889
dc.language.isoeng
dc.publisherELSEVIER SCI LTDeng
dc.relation.ispartofEnvironmental Pollution
dc.rightsrestrictedAccesseng
dc.rights.holderCopyright ELSEVIER SCI LTDeng
dc.subjectBiomonitoringeng
dc.subjectTree barkeng
dc.subjectTree ringeng
dc.subjectDendrochemistryeng
dc.subjectMegacitieseng
dc.subject.othertree-ringseng
dc.subject.otheratmospheric-pollutioneng
dc.subject.othersource apportionmenteng
dc.subject.othervehicle emissionseng
dc.subject.othertrace-elementseng
dc.subject.otherair-pollutioneng
dc.subject.otherurbaneng
dc.subject.otherleadeng
dc.subject.otherpm2.5eng
dc.subject.otherbarkeng
dc.subject.wosEnvironmental Scienceseng
dc.titleSpatial-temporal variability of metal pollution across an industrial district, evidencing the environmental inequality in Sao Pauloeng
dc.typearticleeng
dc.type.categoryoriginal articleeng
dc.type.versionpublishedVersioneng
dspace.entity.typePublication
hcfmusp.author.externalLOCOSSELLI, Giuliano Maselli:Univ Sao Paulo, Inst Biociencias, Sao Paulo, SP, Brazil; Univ Sao Paulo, Inst Estudos Avancados, Sao Paulo, SP, Brazil
hcfmusp.author.externalCHACON-MADRIZ, Katherine:Univ Estadual Campinas, Inst Quim, Campinas, SP, Brazil
hcfmusp.author.externalARRUDA, Marco Aurelio Zezzi:Univ Estadual Campinas, Inst Quim, Campinas, SP, Brazil
hcfmusp.author.externalCAMARGO, Evelyn Pereira de:Univ Sao Paulo, Inst Biociencias, Sao Paulo, SP, Brazil
hcfmusp.author.externalKAMIGAUTI, Leonardo Yoshiaki:Univ Sao Paulo, Inst Astron & Geofis, Sao Paulo, SP, Brazil
hcfmusp.author.externalTRINDADE, Ricardo Ivan Ferreira da:Univ Sao Paulo, Inst Astron & Geofis, Sao Paulo, SP, Brazil
hcfmusp.author.externalANDRADE, Maria de Fatima:Univ Sao Paulo, Inst Astron & Geofis, Sao Paulo, SP, Brazil
hcfmusp.author.externalANDRE, Carmen Diva Saldiva de:Univ Sao Paulo, Inst Matemat & Estat, Sao Paulo, SP, Brazil
hcfmusp.author.externalSINGER, Julio M.:Univ Sao Paulo, Inst Matemat & Estat, Sao Paulo, SP, Brazil
hcfmusp.author.externalSAIKI, Mitiko:IPEN CNEN SP, Inst Pesquisas Energet & Nucl, Sao Paulo, SP, Brazil
hcfmusp.author.externalZACCARELLI-MARINO, Maria Angela:Fac Med ABC, Sao Paulo, SP, Brazil
hcfmusp.author.externalBUCKERIDGE, Marcos Silveira:Univ Sao Paulo, Inst Biociencias, Sao Paulo, SP, Brazil; Univ Sao Paulo, Inst Estudos Avancados, Sao Paulo, SP, Brazil
hcfmusp.citation.scopus13
hcfmusp.contributor.author-fmusphcTIANA CARLA LOPES MOREIRA
hcfmusp.contributor.author-fmusphcPAULO AFONSO DE ANDRE
hcfmusp.contributor.author-fmusphcPAULO HILARIO NASCIMENTO SALDIVA
hcfmusp.description.articlenumber114583
hcfmusp.description.volume263
hcfmusp.origemWOS
hcfmusp.origem.scopus2-s2.0-85083481939
hcfmusp.origem.wosWOS:000539426400134
hcfmusp.publisher.cityOXFORDeng
hcfmusp.publisher.countryENGLANDeng
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